Product ID:VOLATILES, BASE/NEUTRALS ACIDS, PCBS PESTICIDES
MSDS Date:03/15/1992
FSC:6840
NIIN:00N045698
MSDS Number: BTMLZ

ENVIRONMENTAL RESOURCE ASSOC

5540 MARSHALL ST
ARVADA, CO 80002
US

Emergency Phone: 303-431-8454

Info Phone: 303-431-8454

Preparer: DANIEL A. GOLSTEIN MD

Cage: 1R664

ENVIRONMENTAL RESOURCE ASSOCIATES

ARVADA, CO 80002 US

Telephone: 303-431-8454

Cage: 1R664

250 MG/L

Fraction By Weight: SEE ING

OSHA PEL N/K

ACGIH TLV: N/K

250 MG/L

Fraction By Weight: SEE ING

OSHA PEL N/K

ACGIH TLV: N/K

5 MG/L

CAS: 1336-36-3

RTECS: TQ1350000

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

25 MG/L

Fraction By Weight: SEE ING

OSHA PEL N/K

ACGIH TLV: N/K

METHANOL; (METHYL ALCOHOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99.2%

OSHA PEL 200 PPM;250 STEL, S

ACGIH TLV: 200 PPM;250 STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

200 MG/L

RTECS: 9999999VO

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:IRRITATES & DAMAGES ALL TISSUES. MAY
CAUSE LIVER, KIDNEY AND LUNG DAMAGE. MAY CAUSE CARDIAC ARRHYTHMIA,
MAY SENSITIZE THE HEART. MAY CAUSE IRRITANT DERMATITIS, ALLERGIC
DERMATITIS OR CHLORACNE. MAY CA USE CANCER IN HUMANS. INGEST: MAJOR
HAZDUE TO METHANOL. QUANTITIES AS SMALL AS 1 OZ (30 CC) MAY CAUSE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:POLYCHLORINATEDBIPHENYLS: IARC
MONOGRAPHS, SUPPLEMENT, VOL 7, PG 322, 1987: GRP 2A. NTP 6TH ANNUAL
REPORT (SUPP DATA)
Effects of Overexposure:HLTH HAZ: PERMANENT BLINDNESS. WILL ALSO CAUSE
ACIDOSIS, ALCOHOL INTOXICATION. IF INGESTED SEEK MEDICAL ADVICE
IMMEDIATELY. SIGNS & SYMPS: RED, DRY SCALY SKIN; CRACKING & WEEPING
SKIN; COUGH AND WHEEZ ING. JAUNDICE, NAUSEA, VOMITING; UREMIA;
ACIDOSIS.
Medical Cond Aggravated by Exposure:DERMATITIS. LIVER DISEASE, KIDNEY
DISEASE, ALCOHOL INTOXICATION.

First Aid:INHAL: REMOVE FROM EXPOURE. BE PREPARED TO DO CPR. INGEST:
GIVE SYRUP OF IPECAC 60 CC WITH 180 CC WATER IF SWALLOWED. SKIN:
WASH SKIN. EYE: IMMEDIATELY FLUSH WITH POTABLE WATER FOR A MINIMUM
OF 15 MIN . SEEK ASSISTANCE FROM MD .

Flash Point Method:TOC
Flash Point:59.9F,15.5C
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL FOAM.
Fire Fighting Procedures:IF LARGE AMOUNTS INVOLVED IN FIRE USE NIOSH/
MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . WET DOWN TO KEEP
FROM EXPLODING. USE WATER MIST/ALCOHOL FOAM
Unusual Fire/Explosion Hazard:MAY FORM CARBON MONOXIDE, PHOSGENE AND
CARBONYL BROMIDE WHEN INVOLVED IN FIRE.

Spill Release Procedures:DAM UP AND ABSORB. VENTILATE THE AREA. CALL
CLEANUP TEAM. DO NOT WASH TO DRAINS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID FREEZING, BREAKAGE. STORE AWAY
FROM CHROMIC ANHYDRIDE, IODINE, ETHANOL, MERCURIC OXIDE, KOH, NAOH,
CHLOROFORM, LEAD PERCHLORATE.
Other Precautions:HANDLE WITH CARE! MATERIAL CONTAINS CARCINOGENS.

Respiratory Protection:NIOSH/MSHA APPROVED ORGANIC VAPOR CARTRIDGE,
FULL FACE PIECE; OR SELF CONTAINED OR AIR SUPPLIED RESPIRATOR.
Ventilation:LOCAL EXHAUST: USE IN HOOD. SPECIAL: VENTILATE SPILLS.
Protective Gloves:VITON OR NEOPRENE.
Eye Protection:ANSI APPROVED SPLASH GOGGLES .
Other Protective Equipment:LABORATORY COAT, CLOSED SHOES. EMERGENCY
EYEWASH & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA .
Work Hygienic Practices:USE CAREFUL LABORATORY TECHNIQUE. AVOID HAND
CONTACT. MEDICAL MONITORING WITH ANNUAL HISTORY, PHYSICAL AND LAB
WORK.
Supplemental Safety and Health
EXPLAN OF CARCIN: ON CARCINOGENS, 1991: ANTICIPATED TO BE CARCINOGEN.
ANIMAL: TUMORS OF LIVER, PITUITARY GLAND, LEUKEMIA.

HCC:F3
Boiling Pt:B.P. Text:148F,65C
Vapor Density:1.11
Spec Gravity:0.792 (H2O=1)
Evaporation Rate & Reference:NOT KNOWN.
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS LIQUID. ORGANIC ODOR.

Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:MAY FORM CARBON MONOXIDE, PHOSGENE,
AND CARBONYL BROMIDE WHEN INVOLVED IN FIRE.

Waste Disposal Methods:ABSORB AND INCINERATE OR DISPOSE AS HAZARDOUS
WASTE. DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.